Val Kilmer was absolutely approached to star in what would eventually become Batman and Robin, as the actor also discloses in Val. However, he would reject the part outright because of two important factors. Contractually, Kilmer was already committed to play the lead in The Saint, so he wouldn’t have been able to meet the quick turnaround Warner Bros. was looking for. But even if he didn’t have that part on his docket, it doesn’t sound like he’d have wanted to play the role anyway. All falling down to the suit, Val Kilmer further explained his isolation thusly:
Source: Cinema Blend